Is hydrogen peroxide flammable

 

Conc. Greater than or equal to 20%: CORROSIVE

Conc. Below 20%: IRRITANT

OMIKRON GmbH - Fine Chemicals division
Handling instructions (no Safety data sheet according to EC standard)
for item no .: 100547 - 102840

Hydrogen peroxide solution

Molecular formula: H2O2 * Molar mass 34.02 g / mol * CAS No. [7722-84-1] * EINECS no. (EG-No.): 231-765-0 * UN-No .: 2014
[Water-clear, colorless, easily mobile, odorless, caustic and oxidizing liquid]
Other name (s): hydrogen peroxide (obsolete), perhydrol; eng .: hydrogen peroxide

Hazard warnings: Risk of fire in contact with flammable substances. Causes chemical burns.

Hydrogen peroxide, especially in its more concentrated form, develops a strong one Caustic effect on skin, mucous membranes and eyes. Contact with unprotected skin / textiles also causes white discoloration through fading. Ingestion leads to severe abdominal pain as well as nausea and vomiting. There is a risk of gastric perforation and internal bleeding after the ingestion of larger amounts (therefore risk of death!) Vapors or atomized droplets of the substance, depending on the amount, cause irritation or severe burns to the mucous membrane of the eyes and the airways / lungs. With prolonged exposure to more concentrated solutions on the eyes Risk of blindness!

Contact with impurities (especially with metals) can lead to very rapid decomposition of the solution. This releases a lot of oxygen and heat, which can cause the liquid to splash or the storage container to burst. Contact of hydrogen peroxide solution with flammable materials can cause a fire.

The hazard warnings (R-phrases) and safety advice (S-phrases, see below) on the hazardous substance labeling on the container and in this leaflet are for your convenience security!

Substances to be avoided: Violent reaction with metals, especially with those in Powder form (Aluminum, magnesium, zinc, iron, etc.), alkali metals, metal oxides, aldehydes, alcohols, amines, ammonia, carbon, hydrazine, hydrides, flammable substances, oxidizing agents (e.g. permanganates), ethers, acids, anhydrides. Attention! The formation is extremely dangerous with organic substances / liquids such as methenamine (hexamethylenetetramine) and acetone explosive peroxides (e.g. tricycloacetone peroxide) possible. Conditions under which such substances can arise must be carefully avoided.

Hazardous decomposition products:

Oxygen produced is not itself dangerous; In the event of stormy formation or the formation of gases in the closed vessel, however, dangerous overpressure can arise (bursting, bursting).

Environmental toxicity:

Toxic effects on fish and plankton in higher concentrations. As little as 40 mg per liter of water are poisonous for trout. The disturbance threshold for fish nutrients is> 2500 mg / L

WGK 0 (generally not hazardous to water). Rapid reduction or decomposition to pure water and oxygen takes place in the soil and water. However, leftovers are essential for one Pollutant collection pointor hand in pollutant mobile, do not allow it to enter the sewage system or surface water!

Fish toxicity (golden orfe) LC50 (48 h): 35 mg / L (concentration based on hydrogen peroxide 100%).

Protective measures

and rules of conduct for storage and handling:

Keep substance cool (below 15 ° C), dark, in a well-ventilated place, tightly closed and out of the reach of children. Do not store together with flammable materials. Do not bring together with flammable materials. Protect from heat. Keep contaminants away. Only use containers with overpressure protection!

Security advice: (EC marking) Keep locked up and out of the reach of children. Store cool. In case of contact with skin, wash off immediately with plenty of water. Wear suitable protective clothing and eye / face protection when working. In the event of an accident or if you feel unwell, seek medical advice immediately (show this label if possible).
Respiratory system: Avoid inhalation of the vapors / aerosols. Respiratory protection required when large amounts of vapors and aerosols are generated.

Eyes:Absolutely Use laboratory safety glasses with side protection and upper eye area cover. In the event of contact with the eyes, rinse immediately and thoroughly with running water (at least 15 minutes with the eyelids held apart) and consult a doctor / ophthalmologist immediately. There is a risk of blindness!

If there is a risk of exothermic reactions with the intended use, a Full face shield to be used according to DIN.

Hands: Suitable protective gloves that are resistant to the solution (clarify suitability with supplier!).
Body: Wear suitable protective clothing when working. Avoid splashing at all costs.

Rules of conduct in the event of danger or fire:

Methods for cleaning up: Absorb with liquid-binding material (e.g. vermiculite, Chemizorb). Send for proper disposal. Rinse away any residues with plenty of water. Post-cleaning.

First aid measures:

After eye contact: Rinse under running water for several minutes (at least 15 min) with the eyelid wide open. Consult an ophthalmologist.
After skin contact: Wash off with plenty of water, dab with polyethylene glycol 400.
After inhalation: spend affected person in fresh air; Call a doctor.
After swallowing: give plenty of water or milk to drink in small sips. Avoid vomiting. Call a doctor.
After clothing contact: Remove contaminated clothing and rinse affected areas with water.

Statutory Regulations:

Ordinance on Hazardous Substances (GefStoffV) and TRGS regulations; Chemicals Prohibition Ordinance (ChemVerbotsV)
Maximum workplace concentration (MAK value): 1.4 mg / m3.

Disclaimer:
Application, use, processing and storage of the purchased products are exclusively the responsibility of the customer after delivery.
Claims for damages due to impossibility of performance, due to non-fulfillment, positive breach of contract, negligence in the conclusion of the contract and tortious acts are excluded both against the seller and against her vicarious agents or vicarious agents, unless the damage was caused intentionally or through gross negligence on the part of the seller has been.
This applies in particular to damage and defects that arise during storage and handling of the chemicals.

OMIKRON GmbH * Marktplatz 5 * 74382 Neckarwestheim * Created on December 10th, 1999 * Last change of the document on April 1st, 2005


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